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Distribution of relaxation times : Foundations, methods, diagnostics, and prognosis for electrochemical systems

DOI zum Zitieren der Version auf EPub Bayreuth: https://doi.org/10.15495/EPub_UBT_00009416
URN to cite this document: urn:nbn:de:bvb:703-epub-9416-5

Title data

Wang, Zilong ; Wang, Yuhao ; Ciucci, Francesco:
Distribution of relaxation times : Foundations, methods, diagnostics, and prognosis for electrochemical systems.
In: Current Opinion in Electrochemistry. Vol. 55 (2026) . - 101789.
ISSN 2451-9103
DOI der Verlagsversion: https://doi.org/10.1016/j.coelec.2025.101789

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Project information

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Project's official title
Project's id
Enthüllung der mikrostrukturellen und elektrochemischen Entwicklung einer Si/Sn-Nanofaserverbundanode für Lithium-Ionen-Batterien
533115776
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Project financing: Deutsche Forschungsgemeinschaft

Abstract

The distribution of relaxation times (DRT) has become an indispensable technique for interpreting electrochemical impedance spectroscopy. This review traces the evolution of DRT from a powerful deconvolution tool for gaining mechanistic insights into a predictive engine for diagnostics and state estimation in fields such as batteries and fuel cells. The technique’s intuitive appeal is challenged by its mathematically ill-posed nature, creating a “credibility gap” where subjective choices can yield misleading artifacts. Recent methodological advances in Bayesian and entropy-based frameworks provide greater robustness and uncertainty quantification. The path forward requires establishing a comprehensive analytical ecosystem built on community standards, benchmark datasets, and transparent reporting. This current opinion urges the community to embrace rigor and transform DRT from a specialized, expert-level tool into a reliable and reproducible cornerstone of electrochemical analysis.

Further data

Item Type: Article in a journal
DDC Subjects: 600 Technology, medicine, applied sciences > 620 Engineering
Institutions of the University: Faculties > Faculty of Engineering Science > Chair Electrode Design of Electrochemical Energy Storage Systems > Chair Electrode Design of Electrochemical Energy Storage Systems - Univ.-Prof. Dr. Francesco Ciucci
Research Institutions > Central research institutes > Bayerisches Zentrum für Batterietechnik - BayBatt
Faculties
Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Electrode Design of Electrochemical Energy Storage Systems
Research Institutions
Research Institutions > Central research institutes
Language: English
Originates at UBT: Yes
URN: urn:nbn:de:bvb:703-epub-9416-5
Date Deposited: 12 Jun 2026 12:32
Last Modified: 12 Jun 2026 12:33
URI: https://epub.uni-bayreuth.de/id/eprint/9416

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