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Biobased Immiscible Polylactic Acid (PLA) : Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) Blends: Impact of Rheological and Non-isothermal Crystallization on the Bead Foaming Behavior

DOI zum Zitieren der Version auf EPub Bayreuth: https://doi.org/10.15495/EPub_UBT_00007988
URN to cite this document: urn:nbn:de:bvb:703-epub-7988-9

Title data

Brütting, Christian ; Dreier, Julia ; Bonten, Christian ; Ruckdäschel, Holger:
Biobased Immiscible Polylactic Acid (PLA) : Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) Blends: Impact of Rheological and Non-isothermal Crystallization on the Bead Foaming Behavior.
In: Journal of Polymers and the Environment. Vol. 32 (2024) Issue 9 . - pp. 4182-4195.
ISSN 1572-8919
DOI der Verlagsversion: https://doi.org/10.1007/s10924-024-03186-9

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Project information

Project financing: Deutsche Forschungsgemeinschaft

Abstract

Nowadays, bead foams are of great interest due to their high lightweight potential. The processing of such foams strongly depends on the crystallization and rheological behavior of the polymers used. By blending polymers, these properties can be tailored to obtain beaded foams with low density, small cell size and high cell density. As a bio-based polymer, PLA is of great interest due to its renewable carbon source. PLA suffers from its low thermal and rheological properties, which can be compensated by using blends. The correlation between the PLA/PHBV ratio and the rheological as well as the crystallization behavior was investigated. The use of PHBV as a minor phase significantly changes the rheological properties and increases the crystallization behavior of PLA. These findings were applied to the foam extrusion process to obtain low density bead foams. Bead foams with densities below 100 kg/m3, mean cell sizes below 50 µm and cell densities of 1 × 107 cells/cm3 were obtained.

Further data

Item Type: Article in a journal
Keywords: Biopolymer blend; Biofoam; PLA; PHBV; Bead foam extrusion; Biopolymer
DDC Subjects: 600 Technology, medicine, applied sciences > 620 Engineering
Institutions of the University: Faculties > Faculty of Engineering Science > Chair Polymer Materials > Chair Polymer Materials - Univ.-Prof. Dr.-Ing. Holger Ruckdäschel
Research Institutions > Affiliated Institutes > Bavarian Polymer Institute (BPI)
Faculties
Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Polymer Materials
Research Institutions
Research Institutions > Affiliated Institutes
Language: English
Originates at UBT: Yes
URN: urn:nbn:de:bvb:703-epub-7988-9
Date Deposited: 10 Oct 2024 10:25
Last Modified: 10 Oct 2024 10:25
URI: https://epub.uni-bayreuth.de/id/eprint/7988

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