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URN to cite this document: urn:nbn:de:bvb:703-epub-7118-3
Title data
Prucker, Tobias ; Lamberty, Aliena ; Thiessen, Johannes ; König, Matthias ; Jess, Andreas:
Effect of Particle Size and Coke Formation on n-Octane Dehydrogenation.
In: Chemie Ingenieur Technik.
Vol. 94
(2022)
Issue 11
.
- pp. 1711-1719.
ISSN 1522-2640
DOI der Verlagsversion: https://doi.org/10.1002/cite.202200054
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Abstract
The effect of particle size as well as of coke formation on conversion of intermediate chain length paraffins (C6–C9) to the corresponding olefins was investigated on a promoted Pt catalyst with the model substance n-octane. Increasing the particle size leads to pore diffusion limitations and thus to a reduction of the activity for paraffin conversion and of the octene selectivity caused by more pronounced formation of consecutive products (aromatics, octadienes). Both effects are adequately predicted by the developed kinetic model. The activity of dehydrogenation declines with the content of coke, but to a lesser extent than the rate of coke formation, which is beneficial regarding the catalyst lifetime. The initial activity is fully recovered by mild coke burn-off (T < 470 °C).
Further data
| Item Type: | Article in a journal |
|---|---|
| Keywords: | Catalyst deactivation; Internal diffusion limitation; Modeling; n-Octane dehydrogenation |
| DDC Subjects: | 500 Science > 540 Chemistry 600 Technology, medicine, applied sciences > 600 Technology 600 Technology, medicine, applied sciences > 620 Engineering 600 Technology, medicine, applied sciences > 660 Chemical engineering |
| Institutions of the University: | Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Chair Chemical Engineering Faculties > Faculty of Engineering Science > Chair Chemical Engineering > Chair Chemical Engineering - Univ.-Prof. Dr.-Ing. Andreas Jess Faculties |
| Language: | English |
| Originates at UBT: | Yes |
| URN: | urn:nbn:de:bvb:703-epub-7118-3 |
| Date Deposited: | 19 Jul 2023 05:01 |
| Last Modified: | 19 Jul 2023 05:01 |
| URI: | https://epub.uni-bayreuth.de/id/eprint/7118 |
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