Enhancing Hydrogen Storage Capacity of Pd Nanoparticles by Sandwiching between Inorganic Nanosheets

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Ament, Kevin ; Kobayashi, Hirokazu ; Kusada, Kohei ; Breu, Josef ; Kitagawa, Hiroshi:
Enhancing Hydrogen Storage Capacity of Pd Nanoparticles by Sandwiching between Inorganic Nanosheets.
In: Zeitschrift für anorganische und allgemeine Chemie. Bd. 648 (5 März 2022) Heft 10 . - No. e202100370.
ISSN 1521-3749
DOI der Verlagsversion: https://doi.org/10.1002/zaac.202100370

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Abstract

H-2 is regarded to play a crucial role in the transition from a fossil fuel-based energy economy towards an environmentally friendly one. However, storage of H-2 is still challenging, but palladium (Pd) based materials show exciting properties. Therefore, nanoparticulate Pd has been intensely studied for hydrogen storage in the past years. Here, we stabilize Pd nanoparticles by intercalation between inorganic nanosheets of hectorite (NaHec). Compared to nanoparticles stabilized by the polymer polyvinylpyrrolidone (PVP), the H-2 storage capacity was found to be 86 % higher for identical Pd nanoparticles being intercalated between nanosheets. We attribute this remarkably enhanced H-2 storage capacity to the partial oxidation of Pd, as evidenced by X-ray photoelectron spectroscopy (XPS). The higher amount of holes in the 4d band leads to a higher amount of H-2 that can be absorbed when Pd is stabilized between the nanosheets of hectorite compared to the PVP stabilized nanoparticles.