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Compostable and Recyclable Baroplastic Triblock Copolymers Enable Low-Energy Polymer Processing

DOI zum Zitieren der Version auf EPub Bayreuth: https://doi.org/10.15495/EPub_UBT_00009550
URN to cite this document: urn:nbn:de:bvb:703-epub-9550-9

Title data

Xu, Chengzhang ; Yi, Chengwei ; Fulajtar, Emilia ; Ramsperger, Anja ; Brehm, Julian ; Laforsch, Christian ; Schmalz, Holger ; Rosenfeldt, Sabine ; Mansfeld, Ulrich ; Kress, Holger ; Möglich, Andreas ; Greiner, Andreas ; Agarwal, Seema:
Compostable and Recyclable Baroplastic Triblock Copolymers Enable Low-Energy Polymer Processing.
In: Small. Vol. 22 (16 March 2026) Issue 37 . - e14939.
ISSN 1613-6829
DOI der Verlagsversion: https://doi.org/10.1002/smll.202514939

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Project information

Project title:
Project's official title
Project's id
SFB 1357: MIKROPLASTIK – Gesetzmäßigkeiten der Bildung, des Transports, des physikalisch-chemischen Verhaltens sowie der biologischen Effekte: Von Modell- zu komplexen Systemen als Grundlage neuer Lösungsansätze
391977956
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Project financing: Deutsche Forschungsgemeinschaft

Abstract

Baroplastic polymers enable low-energy processing at low temperatures under mild pressure preserving polymer integrity and supporting end-of-life pathways that reduce the formation of persistent microplastic residues. Poly(L-lactide)-block-poly(ethylene glycol)-block-poly(L-lactide) (PLLA-b-PEG-b-PLLA) triblock copolymers demonstrate baroplasticity, enabling ambient temperature processing under moderate pressure. Here, we synthesized and characterized PLLA-b-PEG-b-PLLA with specific block lengths, showing rapid degradation within 2 months under industrial composting conditions and effective chemical and physical recyclability. Low-temperature baroplastic processing preserves the activity of encapsulated heat-sensitive proteins, expanding its application potential. These findings suggest that PLLA-b-PEG-b-PLLA combines sustainable processing, compostability, and recyclability, offering a promising platform for environmentally friendly polymer technologies in packaging, agriculture, and beyond.

Further data

Item Type: Article in a journal
Keywords: baroplastic; biodegradable; block copolymer
DDC Subjects: 500 Science > 500 Natural sciences
500 Science > 530 Physics
500 Science > 540 Chemistry
500 Science > 550 Earth sciences, geology
500 Science > 570 Life sciences, biology
Institutions of the University: Faculties > Faculty of Mathematics, Physics und Computer Science
Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics
Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Professor Experimental Physics VI - Biologial Physics
Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Professor Experimental Physics VI - Biologial Physics > Professor Experimental Physics VI - Biologial Physics - Univ.-Prof. Dr. Holger Kress
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology > Chair Animal Ecology I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology > Chair Animal Ecology I > Chair Animal Ecology I - Univ.-Prof. Dr. Christian Laforsch
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry I - Kolloidale Strukturen und Energiematerialien
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Biochemistry II - Photobiochemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Biochemistry II - Photobiochemistry > Chair Biochemistry II - Photobiochemistry - Univ.-Prof. Dr. Andreas Möglich
Research Networks > Ecology and Environment
Research Networks > Polymers and Interfaces
Research Institutions > Central research institutes > Bayreuth Center of Ecology and Environmental Research- BayCEER
Research Institutions > Affiliated Institutes > Bavarian Polymer Institute (BPI)
Research Institutions > Collaborative Research Centers, Research Unit > SFB 1357 - MIKROPLASTIK
Faculties
Research Networks
Research Institutions
Research Institutions > Central research institutes
Research Institutions > Affiliated Institutes
Research Institutions > Collaborative Research Centers, Research Unit
Language: English
Originates at UBT: Yes
URN: urn:nbn:de:bvb:703-epub-9550-9
Date Deposited: 31 Jul 2026 08:03
Last Modified: 31 Jul 2026 08:03
URI: https://epub.uni-bayreuth.de/id/eprint/9550

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