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Photocatalytic Regioselective C–H Bond Functionalizations in Arenes

DOI zum Zitieren der Version auf EPub Bayreuth: https://doi.org/10.15495/EPub_UBT_00008167
URN to cite this document: urn:nbn:de:bvb:703-epub-8167-9

Title data

Hu, Jun ; Pradhan, Suman ; Waiba, Satyadeep ; Das, Shoubhik:
Photocatalytic Regioselective C–H Bond Functionalizations in Arenes.
In: Chemical Science. Vol. 16 (2025) Issue 3 . - pp. 1041-1070.
ISSN 2041-6539
DOI der Verlagsversion: https://doi.org/10.1039/D4SC07491B

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Abstract

The direct functionalization of C–H bonds has revolutionized the field of synthetic organic chemistry by enabling efficient and atom-economical modification of arenes by avoiding prefunctionalization. However, the inherent challenges of inertness and regioselectivity in different C–H bonds, particularly for distal positions, necessitate innovative approaches. In this aspect, photoredox catalysis by utilizing both transition metal and organic photocatalysts has emerged as a powerful tool for addressing these challenges under mild reaction conditions. This review provides a comprehensive overview of recent progress in regioselective C–H functionalization in arenes via photocatalysis. Emphasizing the strategies for achieving ortho, meta, and para-selectivity, we explore the mechanistic insights, catalyst designs, and the novel methodologies that have expanded the scope of C–H bond functionalization. This discussion aims to offer valuable perspectives for advancing the field and developing more efficient and sustainable synthetic methodologies.

Further data

Item Type: Article in a journal
DDC Subjects: 500 Science > 540 Chemistry
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry I - Photo- und Elektrokatalyse für Nachhaltigkeit > Chair Organic Chemistry I - Photo- und Elektrokatalyse für Nachhaltigkeit - Univ.-Prof. Dr. Shoubhik Das
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry I - Photo- und Elektrokatalyse für Nachhaltigkeit
Language: English
Originates at UBT: Yes
URN: urn:nbn:de:bvb:703-epub-8167-9
Date Deposited: 31 Jan 2025 06:52
Last Modified: 31 Jan 2025 06:52
URI: https://epub.uni-bayreuth.de/id/eprint/8167

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