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Synthese und Anwendung von HDPE/iPP Blockcopolymeren auf Basis der KKTP

DOI zum Zitieren der Version auf EPub Bayreuth: https://doi.org/10.15495/EPub_UBT_00007963
URN to cite this document: urn:nbn:de:bvb:703-epub-7963-1

Title data

Wolff, Patrick:
Synthese und Anwendung von HDPE/iPP Blockcopolymeren auf Basis der KKTP.
Bayreuth , 2024 . - XIII, 141 P.
( Doctoral thesis, 2024 , University of Bayreuth, Faculty of Biology, Chemistry and Earth Sciences)

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Abstract

HDPE-iPP Blockcopolymere können als Phasenvermittler für unmischbare Polyolefinblends eingesetzt werden. In dieser Arbeit werden neuartige Syntheserouten für unterschiedliche Typen von HDPE-iPP Blockcopolymeren vorgestellt. Durch die koordinative Kettentransferpolymerisation kann eine außergewöhnlich hohe Effizienz bei gleichzeitig hoher Kontrolle über die Polymerarchitektur bei der Polymerisation erreicht werden. Es wurden HDPE-iPP Diblockcopolymere und iPP-g-HDPE Graftcopolymere hergestellt, in ihrer Wirkung als Phasenvermittler untersucht und Konzepte für die Phasenvermittlung aufgestellt.

Abstract in another language

HDPE-iPP block copolymers can be used as compatibilizers for immiscible polyolefin blends. In this work, novel synthesis routes for different types of HDPE-iPP block copolymers are presented. Coordinative chain transfer polymerization can achieve exceptionally high efficiency with high control over the polymer architecture during polymerization. HDPE-iPP diblock copolymers and iPP-g-HDPE graft copolymers were produced, their effect as compatibilizers was investigated and concepts for the compatibilization mechanisms were developed.

Further data

Item Type: Doctoral thesis (No information)
Keywords: CCTP; Coordinative Chaintranser Polymerization; Compatibilizer; Recycling;
Blends; Olefin; Block copolymer; Multiblock copolymer; Polymerization,
Living polymerization; Controlled polymerization; Graft copolymer
DDC Subjects: 500 Science > 540 Chemistry
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe
Graduate Schools > University of Bayreuth Graduate School
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II
Graduate Schools
Language: German
Originates at UBT: Yes
URN: urn:nbn:de:bvb:703-epub-7963-1
Date Deposited: 23 Oct 2024 08:48
Last Modified: 23 Oct 2024 08:49
URI: https://epub.uni-bayreuth.de/id/eprint/7963
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