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URN to cite this document: urn:nbn:de:bvb:703-epub-7248-4
Title data
Ramakrishnan, Sitaram ; Matteppanavar, Shidaling ; Schönleber, Andreas ; Patra, Bikash ; Singh, Birender ; Thamizhavel, Arumugam ; Singh, Bahadur ; Ramakrishnan, Srinivasan ; van Smaalen, Sander:
Realization of Z₂ Topological Metal in Single-Crystalline Nickel Deficient NiV₂Se₄.
In: Annalen der Physik.
Vol. 535
(2023)
Issue 6
.
- 2200611.
ISSN 1521-3889
DOI der Verlagsversion: https://doi.org/10.1002/andp.202200611
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Abstract
Abstract Temperature-dependent electronic and magnetic properties are reported for nickel-deficient NiV2Se4. Single-crystal X-ray diffraction shows it to crystallize in the monoclinic Cr3S4 structure type with space group I2/m and vacancies on the Ni site, resulting in the composition Ni0.85V2Se4 in agreement with our electron-probe microanalysis. Structural distortions are not observed down to 1.5 K. Nevertheless, the electrical resistivity shows metallic behavior with a broad anomaly around 150–200 K that is also observed in the heat capacity data. This anomaly indicates a change of state of the material below 150 K. It is believed that this anomaly could be due to spin fluctuations or charge-density-wave fluctuations, where the lack of long-range order is caused by vacancies at the Ni site of Ni0.85V2Se4. The non-linear temperature dependence of the resistivity as well as an enhanced value of the Sommerfeld coefficient γ=104.0(1) mJ mol−1 K−2 suggest strong electron–electron correlations in this material. First-principles calculations performed for NiV2Se4, which are also applicable to Ni0.85V2Se4, classify this material as a topological metal with Z2=(1;110) and coexisting electron and hole pockets at the Fermi level. The phonon spectrum lacks any soft phonon mode, consistent with the absence of periodic lattice distortion in the present experiments.
Further data
| Item Type: | Article in a journal |
|---|---|
| Keywords: | charge-density-waves; non Fermi liquids; topological metals; vacancies |
| DDC Subjects: | 500 Science > 530 Physics |
| Institutions of the University: | Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography > Chair Crystallography - Univ.-Prof. Dr. Sander van Smaalen Faculties Faculties > Faculty of Mathematics, Physics und Computer Science Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences |
| Language: | English |
| Originates at UBT: | Yes |
| URN: | urn:nbn:de:bvb:703-epub-7248-4 |
| Date Deposited: | 17 Oct 2023 06:27 |
| Last Modified: | 17 Oct 2023 06:27 |
| URI: | https://epub.uni-bayreuth.de/id/eprint/7248 |
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