URN to cite this document: urn:nbn:de:bvb:703-epub-7235-3
Title data
Klausfelder, Barbara ; Kempe, Rhett:
A Highly Active Nickel Catalyst for the Selective Hydrogenation of Functionalized Nitroarenes.
In: Zeitschrift für anorganische und allgemeine Chemie.
Vol. 649
(2023)
Issue 14
.
- e202300071.
ISSN 1521-3749
DOI der Verlagsversion: https://doi.org/10.1002/zaac.202300071
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Project information
Project financing: |
Deutsche Forschungsgemeinschaft |
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Abstract
Abstract The catalytic hydrogenation of nitroarenes using hydrogen gas as reducing agent to form substituted aniline derivates is an important reaction in industry and academic research. Here, we report on the nitroarene hydrogenation capability of a nanostructured nickel catalyst synthesized from a nickel salen complex and a commercially available porous silica support. Our catalyst allows the selective hydrogenation of nitroarenes under mild conditions while tolerating various functional groups and hydrogenation-sensitive examples such as iodine, nitrile or olefinic groups. The use of the nickel salen complex as metal precursor is crucial for the high activity and selectivity observed.
Further data
Item Type: | Article in a journal |
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Additional notes (visible to public): | Dieser Artikel erscheint außerdem in: Hot Topic: Earth-Abundant Transition Metal Catalysis |
Keywords: | nickel catalyst; selective hydrogenation; sustainable catalysis; nitroarene |
DDC Subjects: | 500 Science > 540 Chemistry |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II |
Language: | English |
Originates at UBT: | Yes |
URN: | urn:nbn:de:bvb:703-epub-7235-3 |
Date Deposited: | 16 Oct 2023 05:37 |
Last Modified: | 16 Oct 2023 05:38 |
URI: | https://epub.uni-bayreuth.de/id/eprint/7235 |