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Repulsive Osmotic Delamination : 1D Dissolution of 2D Materials

DOI zum Zitieren der Version auf EPub Bayreuth: https://doi.org/10.15495/EPub_UBT_00007119
URN to cite this document: urn:nbn:de:bvb:703-epub-7119-3

Title data

Dudko, Volodymr ; Khoruzhenko, Olena ; Weiß, Sebastian ; Daab, Matthias ; Loch, Patrick ; Schwieger, Wilhelm ; Breu, Josef:
Repulsive Osmotic Delamination : 1D Dissolution of 2D Materials.
In: Advanced Materials Technologies. Vol. 8 (2023) Issue 3 . - 2200553.
ISSN 2365-709X
DOI der Verlagsversion: https://doi.org/10.1002/admt.202200553

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Abstract

2D materials have proved their potential in nearly every area of material science and chemistry. Unfortunately, large-scale production of nanosheets is not straightforward. Current methods suffer from low yield, uncontrollable defects, and requires a high-energy input. There is always a tradeoff between high quality and high yield. In this review, the alternative is highlighted to existing methods of 2D nanosheet production - 1D dissolution, historically known as osmotic swelling. As a thermodynamically driven, and therefore spontaneous, process it provides numerous benefits such as high aspect ratio and defect-free nanosheets with a quantitative yield. In this review, the theory behind this process is discussed, compare it with the existing methods, and highlight the key features that allow to extend 1D dissolution to different charged layered materials. Moreover, the applications in which nanosheets obtained by 1D dissolution proved to be advantageous due to their unique, processing-related features are discussed.

Further data

Item Type: Article in a journal
Keywords: 2-DIMENSIONAL MATERIALS; CRYSTAL-STRUCTURE; NANOCOMPOSITE HYDROGELS; NANOSHEETs CRYSTALLITES; HYDROXIDE NANOSHEETS; ELECTRON-MICROSCOPY; LAYERED SILICATES; BARRIER COATINGS; EXFOLIATION; GRAPHENE
DDC Subjects: 500 Science > 540 Chemistry
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Colloids for Electrochemical Energy storage > Chair Chair Inorganic Colloids for Electrochemical Energy storage - Univ.-Prof. Dr. Josef Breu
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Colloids for Electrochemical Energy storage
Language: English
Originates at UBT: Yes
URN: urn:nbn:de:bvb:703-epub-7119-3
Date Deposited: 19 Jul 2023 05:08
Last Modified: 19 Jul 2023 05:09
URI: https://epub.uni-bayreuth.de/id/eprint/7119

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