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Magnetic NiFe₂O₄ Nanoparticles Prepared via Non-Aqueous Microwave-Assisted Synthesis for Application in Electrocatalytic Water Oxidation

DOI zum Zitieren der Version auf EPub Bayreuth: https://doi.org/10.15495/EPub_UBT_00006165
URN to cite this document: urn:nbn:de:bvb:703-epub-6165-8

Title data

Simon, Christopher ; Zakaria, Mohamed Barakat ; Kurz, Hannah ; Tetzlaff, David ; Blößer, André ; Weiß, Morten ; Timm, Jana ; Weber, Birgit ; Apfel, Ulf-Peter ; Marschall, Roland:
Magnetic NiFe₂O₄ Nanoparticles Prepared via Non-Aqueous Microwave-Assisted Synthesis for Application in Electrocatalytic Water Oxidation.
In: Chemistry : a European Journal. Vol. 27 (2021) Issue 68 . - pp. 16990-17001.
ISSN 1521-3765
DOI der Verlagsversion: https://doi.org/10.1002/chem.202101716

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Abstract

Phase-pure spinel-type magnetic nickel ferrite (NiFe₂O₄) nanocrystals in the size range of 4 to 11 nm were successfully synthesized by a fast and energy-saving microwave-assisted approach. Size and accessible surface areas can be tuned precisely by the reaction parameters. Our results highlight the correlation between size, degree of inversion, and magnetic characteristics of NiFe₂O₄ nanoparticles, which enables fine-tuning of these parameters for a particular application without changing the elemental composition. Moreover, the application potential of the synthesized powders for the electrocatalytic oxygen evolution reaction in alkaline media was demonstrated, showing that a low degree of inversion is beneficial for the overall performance. The most active sample reaches an overpotential of 380 mV for water oxidation at 10 mA cm−2 and 38.8 mA cm−2 at 1.7 V vs. RHE, combined with a low Tafel slope of 63 mV dec−1.

Further data

Item Type: Article in a journal
Keywords: degree of inversion; microwave synthesis; nanoparticles; oxygen evolution reaction; spinelferrites
DDC Subjects: 500 Science > 540 Chemistry
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV
Language: English
Originates at UBT: Yes
URN: urn:nbn:de:bvb:703-epub-6165-8
Date Deposited: 28 Apr 2022 09:25
Last Modified: 28 Apr 2022 09:25
URI: https://epub.uni-bayreuth.de/id/eprint/6165

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