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Interfacial Polymerization at the Alkane/Ionic Liquid Interface

DOI zum Zitieren der Version auf EPub Bayreuth: https://doi.org/10.15495/EPub_UBT_00005777
URN to cite this document: urn:nbn:de:bvb:703-epub-5777-1

Title data

Liu, Chang ; Yang, Jing ; Guo, Bian‐Bian ; Agarwal, Seema ; Greiner, Andreas ; Xu, Zhi‐Kang:
Interfacial Polymerization at the Alkane/Ionic Liquid Interface.
In: Angewandte Chemie. Vol. 60 (2021) Issue 26 . - pp. 14636-14643.
ISSN 1521-3757
DOI der Verlagsversion: https://doi.org/10.1002/ange.202103555

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Abstract

Polymerization at the liquid–liquid interface has attracted much attention for synthesizing ultrathin polymer films for molecular sieving. However, it remains a major challenge to conduct this process outside the alkane–water interface since it not only suffers water-caused side reactions but also is limited to water-soluble monomers. Here, we report the interfacial polymerization at the alkane/ionic liquid interface (IP@AILI) where the ionic liquid acts as the universal solvent for diversified amines to synthesize task-specific polyamide nanofilms. We propose that IP@AILI occurs when acyl chloride diffuses from the alkane into the ionic liquid instead of being triggered by the diffusion of amines as in the conventional alkane–water system, which is demonstrated by thermodynamic partitioning and kinetic monitoring. The prepared polyamide nanofilms with precisely adjustable pore sizes display unprecedented permeability and selectivity in various separation processes.

Further data

Item Type: Article in a journal
Keywords: interfacial polimerization; ionic liquids; membranes; nanofilms; polyamides
DDC Subjects: 500 Science > 540 Chemistry
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Profile Fields > Advanced Fields > Polymer and Colloid Science
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Profile Fields
Profile Fields > Advanced Fields
Language: English
Originates at UBT: Yes
URN: urn:nbn:de:bvb:703-epub-5777-1
Date Deposited: 14 Sep 2021 08:06
Last Modified: 14 Sep 2021 08:06
URI: https://epub.uni-bayreuth.de/id/eprint/5777

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